CHEMISTRY 3020            
ORGANIC CHEMISTRY

7:30-9:30 AM M-F                    SUMMER 2009

Instructor Office Phone email
Dr. Crouse 313 Foster Hall 372-3515 dcrouse@tntech.edu
TEXT Organic Chemistry (2nd Ed.) Janice G. Smith

LECTURE SCHEDULE

DAY

CH

TOPICS

PROBLEMS

JUNE 29

 13 3010 Review
Mass spectrometry (MS), isotope peaks, cleavage		 13:  17-19,21,23-25,
       27-29,31-36,39,42

JUNE 30

13
14

 Infrared spectroscopy (IR), bond vibrations, absorptions
Nuclear magnetic resonance, theory, 1H number & position of signals		 14:  33,35,37-40,42-51,
       57-60

JULY
1

14

 NMR, splitting, integration, interpretation, 13C spectra   -

JULY
2

 15 Radicals, alkane halogenation, mechanism,  15:  35,36,39-41,45,46,
       48,51,52,54,55,57,
       59,60,63,68-70,72 

JULY
3

 - NO CLASS -

JULY
6

 15
16		 Radical addition, allylic substitution
Conjugated systems, allylic ions, dienes		 16: 29,30,33,35,36,
       38-40,42-44,47,48,
       50,51,55,57-60

JULY
7

 16 Molecular orbitals, 1,2 vs 1,4 addition,
kinetic vs thermodynamic, Diels-Alder,
UV-visible spectroscopy		 -  

JULY
8

 17 Benzene, naming, aromaticity, Huckel 
rule, polygon method		 17:  25-31,35,36,38,
       43-50,54

JULY
9

 18 Aromatic substitution, reactions, 
mechanism, substituent effects		 18:  32-35,38,41-43,45,
       46,48-51,53,54,56,
       58,60,65

JULY 10

 18
19		 Benzene derivatives, side chain rxns
Carboxylic acids, naming, physical 
properties, preparation		 19:  28,29,31-33,35-37,
       41,43,45,47,49,51,
       52,55,58,59,61,62

JULY 13

 19 Reactions, acidity, substituent effects -

JULY 14

 19
20		 Benzoic, sulfonic, amino acids
Aldehydes/ketones, rxns, reduction		 Exam 1 (Chap. 13-18) 

JULY 15

 20 Acid reduction, aldehyde oxidation,
organometallics, synthesis, protecting groups		 20:  37,38,40,41,43,44,
       47,48,51,53-56,58,
       60,61

JULY 16

 21 Aldehyde/ketone preparation, physical
properties, nucleophilic addition		 21:  43,44,46,47,49,
       51-53,58,61,62,68,
       71,72,74-76,82,84,
       87
JULY 17 21
22		 Wittig rxn, amine additions, acetals
Acid derivatives, structure, naming		 22:  42-44,47-54,58,60,
       62,67,72,75,76,79,
       80
JULY 20 22 Rxns of esters, amides, anhydrides, acid chlorides, nucleophilic acyl sub'n -  
JULY 21 23 Enolates, malonic & acetoacetic ester syntheses, a-halogenation 23:  29,31,32,35,40,
       42-44,46,47,50,51,
       53,54,56-59,62
JULY 22 24 Condensations: Aldol, Claisen, Michael 24: 26,28-30,32,34,35,
      38,39,41,42,44,45,
      49-51,54,56,58,59
JULY 23 25 Amines, structure, naming, physical properties 25: 44,45,48,53,55,
       57-62,64,66,69,74,
       76,79,81-83
JULY 24 25 Amines: preparation, basic character, reactions  Exam 2 (Chap. 19-23) 
JULY 27 27 Carbohydrates: monosaccharides, structure, rxns, di/polysaccharides 27:  
JULY 28 28 Amino acids & proteins 28:  
JULY 29 29 Lipids 29:
JULY 30 - Final Exam -

*TUESDAY, JULY 21: Last day to receive a grade of W.

FINAL EXAM:  THURSDAY, JULY 30, 7:30-9:30 AM, ROOM 220

 
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