CHEM 6210
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Spring 2010 |
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11:15 AM - 12:10 PM |
| Instructor | Office | Phone | |
|---|---|---|---|
| Dr. Crouse | 313 FH | 3515 | dcrouse@tntech.edu |
| Texts | Author | ISBN | Copyright |
|---|---|---|---|
|
Advanced Organic Chemistry |
Reinhard Bruckner |
0-12-138110-2 |
2002 |
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Molecular Orbital Calculations |
John D. Roberts |
see iLearn |
1961 |
Most new graduate students took organic chemistry as sophomores but have had
little exposure since. Because of this, they recall organic as a jumbled,
encyclopedic accumulation of facts, too vast to understand or recall
significant details. In other words, students are typically too busy learning
the bark of every 'tree' to step back and see the 'forest', that is the
broad general principles which govern the physical and chemical properties of
organic compounds.
The purpose of this course is to bridge that gap, between the organic the
student should recall and the mainstream material the student will
encounter in the current literature. To accomplish this, we will deviate from
the classical 'functional group' approach and concentrate on the basic
concepts and mechanisms of organic (and really all) chemistry. This is not to
say that we will not study reactions, but that we will strive to simplify and
highlight the fundamentals common throughout organic reactions. At the same
time, we will introduce the student to new material, hopefully in a manner
which will enable them to understand current literature.
| WEEK OF | CHAP. | TOPICS | Notes |
|---|---|---|---|
| JAN 14 | R-1 | Introduction, basics of bonding & mechanism | Class meets Thursday |
| JAN 18 | R-2 | Wave Mechanics, Huckel MO model | No Class Monday |
| JAN 25 | R-3 | LCAO equations, pi energy | - |
| FEB 1 | B-1 | Radicals - chain mechanisms | - |
| FEB 8 | B-2 | Nucleophilic Substitutions | - |
| FEB 15 | B-2, 3 | Substitutions Additions to olefinic systems |
- |
| FEB 22 | B-3, 4 | Additions Eliminations |
- |
| MAR 1 | B-4 | Elimination processes | Mid-Term Exam |
| MAR 8 | -- | Spring Break | |
| MAR 15 | B-6 | Nucleophilic Acyl Substitutions | - |
| MAR 22 | B-7,8 | Nucleophilic additions Carbonyl additions |
- |
| MAR 29 | B-8, 9 | Carbonyl additions Ylide reactions |
- |
| APR 5 | B-10 | Enolate reactions | - |
| APR 12 | B-11 | Rearrangements | - |
| APR 19 | B-12 | Thermal cycloadditions, Orbital Symmetry | -- |
| APR 26 | B-5 | Aromatic Substitutions | |
| May 3 |
Final Exam: Thursday, May 6, 10:30 AM-12:30 PM, Room 317 FH. |
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For detailed course information, consult the iLearn site
.
Students with a disability requiring accommodations should contact the
Office of Disability Services (ODS). An Accommodation Request (AR) should be
completed as soon as possible, preferably by the end of the first week of the
course. The contact is located in the Roaden University Center, Room 112;
phone 372-6119.
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